Synthesis and characterization of poly(methyl methacrylate) co-doped with Tb(tmhd)3 – Rhodamine B for luminescent optical fiber applications

G. Lesly Jiménez , Ciro Falcony , Magdalena Szumera , Piotr Jeleń , Magdalena Leśniak , Marcin Kochanowicz , Jacek Mariusz Żmojda , Dominik Dorosz , Piotr Miluski

Abstract

Currently, there is a growing interest in the development of multi-colored materials based on the combination of two or more systems (organic or inorganic) as a strategy to take advantage of their combined physical or chemical properties. These multi-colored materials have found potential applications as sensors, amplifiers, and optical fibers. In this work, the physical characteristics of poly(methyl methacrylate) (PMMA) doped with Terbium(III)-tris-(2,2,6,6-tetramethyl-3,5-heptanedionate) (Tb(tmhd)3)at1.57–1.58 mmol and Rhodamine B (RhB) at different concentrations were analyzed. The emission obtained from these samples (multichromophoric samples) varied as function of RhB concentration due to an efficient energy transfer process (33–65%). The role of PMMA as inert matrix that assists in the recombination process was confirmed by FTIR and Raman spectra analysis. More-over, an improvement in thermal resistance of the materials was observed due to the presence of the dopants during the polymerization process.
Author G. Lesly Jiménez
G. Lesly Jiménez,,
-
, Ciro Falcony
Ciro Falcony,,
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, Magdalena Szumera
Magdalena Szumera,,
-
, Piotr Jeleń
Piotr Jeleń,,
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, Magdalena Leśniak
Magdalena Leśniak,,
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, Marcin Kochanowicz (FEE / DEPEPLT)
Marcin Kochanowicz,,
- Department of Electrical Power Engineering, Photonics and Lighting Technology
, Jacek Mariusz Żmojda (FEE / DEPEPLT)
Jacek Mariusz Żmojda,,
- Department of Electrical Power Engineering, Photonics and Lighting Technology
, Dominik Dorosz
Dominik Dorosz,,
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, Piotr Miluski (FEE / DEPEPLT)
Piotr Miluski,,
- Department of Electrical Power Engineering, Photonics and Lighting Technology
Journal seriesSpectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, [Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy], ISSN 1386-1425, (N/A 100 pkt)
Issue year2020
Vol229
Pages1-6
ASJC Classification1602 Analytical Chemistry; 1607 Spectroscopy; 3105 Instrumentation; 3107 Atomic and Molecular Physics, and Optics
DOIDOI:10.1016/j.saa.2019.117893
Internal identifierROC 19-20
Languageen angielski
Score (nominal)100
Score sourcejournalList
ScoreMinisterial score = 100.0, 17-02-2020, ArticleFromJournal
Publication indicators Scopus SNIP (Source Normalised Impact per Paper): 2017 = 1.104; WoS Impact Factor: 2018 = 2.931 (2) - 2018=2.665 (5)
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