Spectroscopic properties of antimony modified germanate glass doped with Eu3+ ions

Renata Szal , Jacek Mariusz Żmojda , Marcin Kochanowicz , Piotr Miluski , Jan Dorosz , Magdalena Leśniak , Piotr Jeleń , Bartosz Starzyk , Maciej Sitarz , Marta Kuwik , Joanna Pisarska , Wojciech Andrzej Pisarski , Yuta Iijima , T. Mori , Dominik Dorosz

Abstract

In this work structural and luminescence properties of gallo-germanate glasses were investigated. The mentioned glass system was modified with barium and antimony oxides and doped with Eu3+ ions. The starting glass consisted of barium oxide as a modifier which was then gradually replaced by antimony oxide to form six glass samples. The gallo-germanate glass as a low-phonon host for RE (Rare Earths) ions is a promising material for optoelectronics. However, luminescence properties closely depend on material composition. For this reason, structural changes in studied materials were induced by changing its chemical composition and the luminescence properties were tested. The FT-IR (Fourier-Transform Infrared Spectroscopy) and the Raman spectra of studied glasses illustrate the tendency to increasing quantity of bridging oxygen connecting germanium ions and decreasing quantity of non-bridging oxygen along with antimony oxide addition. Simultaneously the BP (Boson Peak) measurements and emission spectra of Eu3+ ions show an increasing tendency to the examined glass structure ordering along with modifier oxide addition.
Author Renata Szal
Renata Szal,,
-
, Jacek Mariusz Żmojda (FEE / DEPEPLT)
Jacek Mariusz Żmojda,,
- Department of Electrical Power Engineering, Photonics and Lighting Technology
, Marcin Kochanowicz (FEE / DEPEPLT)
Marcin Kochanowicz,,
- Department of Electrical Power Engineering, Photonics and Lighting Technology
, Piotr Miluski (FEE / DEPEPLT)
Piotr Miluski,,
- Department of Electrical Power Engineering, Photonics and Lighting Technology
, Jan Dorosz (FEE / DEPEPLT)
Jan Dorosz,,
- Department of Electrical Power Engineering, Photonics and Lighting Technology
, Magdalena Leśniak
Magdalena Leśniak,,
-
, Piotr Jeleń
Piotr Jeleń,,
-
, Bartosz Starzyk
Bartosz Starzyk,,
-
, Maciej Sitarz
Maciej Sitarz,,
-
, Marta Kuwik
Marta Kuwik,,
-
et al.`
Journal seriesCeramics International, ISSN 0272-8842, e-ISSN 1873-3956, (N/A 100 pkt)
Issue year2019
Vol45
No18
Pages24811-24817
Publication size in sheets0.5
ASJC Classification1508 Process Chemistry and Technology; 2503 Ceramics and Composites; 2504 Electronic, Optical and Magnetic Materials; 2505 Materials Chemistry; 2508 Surfaces, Coatings and Films
DOIDOI:10.1016/j.ceramint.2019.08.223
Internal identifierROC 19-20
Languageen angielski
Score (nominal)100
Score sourcejournalList
ScoreMinisterial score = 100.0, 17-02-2020, ArticleFromJournal
Publication indicators Scopus SNIP (Source Normalised Impact per Paper): 2018 = 1.279; WoS Impact Factor: 2018 = 3.45 (2) - 2018=3.187 (5)
Citation count*1 (2020-03-29)
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